2004
Akshay Kumar-Priyanka Chopra(Aitraaz)This one was all about the animal-instincts.
Vivek Oberoi-Aishwarya Rai(Kyun... Ho Gaya Na...)For many they did not work, For me they did. Successful or not, memorable and debated for sure. Also, Aao Na...
Saif Ali Khan-Rani Mukherjee(Hum Tum)
Irrfan Khan-Tabu(Maqbool) Our desi Macbeth and Lady Macbeth.
Abhishek Bachchan-Rani Mukerji(Yuva)Lallan and Shashi,slum-dwellers both of them, redefined the word 'Chemistry'.
Abhay Deol-Ayesha Takia(Socha Na Tha)The beginning of Imtiaz Ali. AND Abhay Deol. Lovable. Believable. A Classic by now.
ShahRukh Khan-Preity Zinta(Veer-Zaara)
Ajay Devgan-Aishwarya Rai(RainCoat)
Emraan Hashmi-Mallika Sherawat(Murder)
2005
Amitabh Bachchan-Rani Mukerji(Black)This might be a controversial mention, but the tenderness and the interdependence between Michelle and Mr.Sahay qualify for one of the most poignant Big-screen experiences for the Bolly-buff in the 00's.
Abhishek Bachchan-Rani Mukerji(Bunty Aur Babli)Rural, rustic, FUN. Delectable.
Shiney Ahuja-Chitrangda Singh) and Kay Kay Menon-Chitrangda Singh(Hazaaron Khwaishein Aisi)
John Abraham-Priyanka Chopra(Karam)
Jimmy Shergill-Minissha Lamba(Yahaan)The mountains and valleys of Kashmir. One taboo love. And a haunting music score. Kabhi kabhi aas-paas chand rehta hai
Saif Ali Khan-Vidya Balan(Parineeta)
Shah Rukh Khan-Rani Mukerji(Paheli) The quaint desert of Rajasthan and allthatresplendence. Visual poetry at its best.
Rajpal Yadav-Rituparna Sengupta(Main Meri Patni Aur Woh)
Sanjay Suri-Purab Kohli(My Brother Nikhil)The first time that homosexuality was not an issue of ridicule.
2006
Akshay Kumar-Katrina Kaif(Humko Deewana Kar Gaye) Their first outing together. Also, the only one in which the chemistry worked.
Ajay Devgan-Kareena Kapoor(Omkara) He was Othello, she was Desdemona. It was Uttar Pradesh, but together they worked magic in a premise removed from the original Shakespearean era.
Shah Rukh Khan-Preity Zinta,Shah Rukh Khan-Rani Mukerji and Abhishek Bachchan-Rani Mukerji(Kabhi Alvida Na Kehna) Nobody expected KANK from Karan Johar. Reason they were pissed off after the movie. Also, this one had every grave situation gift-wrapped in a lot of glitz and glamorous chutzpah,so things looked fake in parts. But there was no denying the chemistry and currents among all the leads.
Rahul Bose-Mallika Sherawat(Pyar Ke Side Effects)Atypical. Unusual. Unconventional.
Salman Khan-Preity Zinta(Jaan-E-Mann)
Shiney Ahuja-Kangna Ranaut(Woh Lamhe) One of MY personal favorites of the decade.
Hrithik Roshan-Aishwarya Rai(Dhoom 2)Charm of good-looking people(despite the terrible smooch)
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